Catálisis Homogénea

2018

 

129 Multigram Synthesis of Thallium Trispyrazolylborate Compounds

A. Olmos, A. Pereira, T. RodríguezBelderraín, Pedro J. Pérez

Synthesis 2018; 50(17): 3333-3336

 

128. Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles

A. Olmos, R. Gava, B. Noverges, D. Bellezza, K. Jacob,M.Besora,W. M. ChamilSameera,M.Etienne, F. Maseras,G. Asensio, A. Caballero, P. J. Pérez

Angewandte Chemie International Edition, 2018, 57

 

127. Trispyrazolylborate Ligands Supported on Vinylic Addition Polynorbornenes and their Copper Derivatives as Recyclable Catalysts

A. C.Albéniz, J. Á. Molina de la Torre, I. Pérez-Ortega, A. Beltrán, M. Rodríguez, M. M. Díaz-Requejo, P. J. Pérez

Chemistry-A European Journal, 2018

 

126. Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization

V. Postils, M. Rodríguez, G. Sabenya, A. Conde, M. M. Díaz-Requejo, P. J. Pérez, M. Costas, M. Solà, J. M. Luis

ACS Catal., 2018, 8 (5), 4313–4322

 

125. Copper(I)‐arene complexes with a sterically hindered trispyrazolylborate ligand

M. Álvarez, J. Urbano, M. R. Fructos, E. Álvarez, P. J. Pérez

European Journal of Inorganic Chemistry, 2018, 19

 

14. Elucidating the Mechanism of Aryl Aminations Mediated by NHC-Supported Nickel Complexes: Evidence for a Nonradical Ni(0)/Ni(II) Pathway

S. González Rull, I. Funes-Ardoiz, C. Maya, F. Maseras, M. R. Fructos, T. R. Belderrain, and M. Carmen Nicasio

ACS Catal., 2018, 8 (5), 3733–3742

 

123. Discrete Cu(I) complexes for azide-alkyne annulations of small molecules inside mammalian cells

J. Miguel-Ávila, M. Tomás-Gamasa, A. Olmos, P. J. Pérez, J. L. Mascarenas

Chemical Science, 2018, 9, 1947-1952

 

122. Enantio- and Diastereoselective Cyclopropanation of 1-Alkenylboronates: Synthesis of 1-Boryl-2,3-Disubstituted Cyclopropanes.

J. Carreras, A. Caballero, P. J. Pérez

AngewandteChemie (International ed. in English), 2018, 57, 2334-+

 

2017

 

121. A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies

L.Vilella, A. Conde, D. Balcells, M. M. Díaz-Requejo, A. Lledos, P. J.Pérez

Chemical Science, 2017, 8, 8373-8383

 

120. Alkane Carbon-Hydrogen Bond Functionalization as a Tool Toward a Steric Parameter for Hydrotris(pyrazolyl)borate (Tp(x)) Ligands

A. Caballero, P. J. Pérez

Israel Journal of Chemistry, 2017, 57, 1047-1052

 

119. Dimensioning the Term Carbenoid

A. Caballero, P. J. Pérez

Chemistry-A European Journal, 2017, 23, 14389-14393

 

118. Catalytic Nitrene Transfer To Alkynes: A Novel and Versatile Route for the Synthesis of Sulfinamides and Isothiazoles.

M. R. Rodríguez, A. Beltrán, A. L. Mudarra, E. Álvarez, F. Maseras, M. M. Díaz-Requejo, Pedro J. Pérez

AngewandteChemie (International ed. in English), 2017, 10.1002/anie.201705664

 

117. The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(eta2 -N2 C(Ph)CO2 Et)].

S. G. Rull, E. Álvarez, M. R. Fructos, T. R. Belderrain, P. J. Pérez

Chemistry (Weinheim an der Bergstrasse, Germany), 2017, 32, 7667-7671

 

116. Water as the Reaction Medium for Intermolecular C-H Alkane Functionalization in Micellar Catalysis

M. Álvarez, R. Gava, M. R. Rodríguez, S. G. Rull, Pedro J. Pérez

ACS Catalysis, 2017, 5, 3707-3711

 

115. Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines

L. Maestre, R.Dorel, Ó. Pablo, I.Escofet, W. M. C. Sameera, E. Álvarez, F. Maseras, M. M. Díaz-Requejo, A. M. Echavarren, P. J. Pérez

J. Am. Chem. Soc., 2017, 139, 2216

 

114. Mechanistic Studies on Gold-Catalyzed Direct Arene C-H Bond Functionalization by Carbene Insertion: The Coinage-Metal Effect

M. R. Fructos, M.Besora, A. A. C Braga, M. M. Díaz-Requejo, F. Maseras, P. J. Pérez

Organometallics, 2017, 36, 172

 

 

2016

 

113 Homogeneous metal-based catalysis in supercritical carbon dioxide as reaction medium

A. Olmos, G. Asensio, P. J. Pérez

ACS Catal. 2016, 10.1021/6b00848

 

 

112. Iron and Manganese Catalysts for the Selective Functionalization of AreneC(sp2)−H Bonds by Carbene Insertion

A. Conde, G. Sabenya,M. Rodríguez,V.Postils,J. M. Luis, M. M. Díaz-Requejo,M. Costas,P. J. Pérez

AngewandteChemie 2016, 55, 6530–6534

 

 

 

 

111. Gold and diazo reagents: a fruitful tool for developing molecular complexity

M. R. Fructos,M. M. Díaz-Requejo, Pedro J. Pérez

Chem. Commun. 2016, 10.1039/C6CC01958G

 

 

 

 

110. Synthesis and catalytic applications of 1,2,3-triazolylidene gold(I) complexes in silver-free oxazoline syntheses and C–H bond activation.

 R. Pretorius, M. R. Fructos, H. Müller-Bunz, R. A. Gossage, P. J. Pérez, M.Albrecht

Dalton Trans, 2016, 45, 14628

 

 

109. Copper-induced ammonia N–H functionalization

M. Álvarez, E. Álvarez,M. R. Fructos, J. Urbano,Pedro J. Pérez

Dalton Trans, 2016, 45, 14591

 

 

108.[2+2] Cycloaddition reactions promoted by group 11 metal-based catalysts

M. R.Fructos, A. Prieto

Tetrahedron 2016, 72,355-36

 

 

 

2015

 

107. Catalytic functionalization of low reactive C(sp3)-H and C(sp2)-H bonds of alkanes and arenes by carbene insertion from diazo compounds

A. Caballero, M. M. Díaz-Requejo, M. R. Fructos, A. Olmos, J. Urbano,P. J.Pérez

Dalton Trans. 2015, DOI:10.1039/C5DT03450G

 

 

 

106. Functionalization of CnH2n+2 Alkanes: Supercritical Carbon Dioxide Enhances the Reactivity towards Primary Carbon-Hydrogen Bonds

R. Gava, A. Olmos, B. Noverges, T. Varea, I. Funes-Ardoiz, T. R. Belderrain, A. Caballero, F. Maseras,G. Asensio, P. J. Pérez

CHEMCATCHEM 2015, 7, 3254-3260

 

 

 

 

105. Catalyst design in the alkane C-H bond functionalization of alkanes by carbene insertion with TpxM complexes (Tpx = hydrotrispyrazolylborate ligand; M = Cu, Ag)

A. Caballero, P. J. Pérez

J. Organomet. Chem. 2015, 793, 108-113

 

 

 

104. Direct Synthesis of Hemiaminal Ethers via a Three-Component Reaction of Aldehydes, Amines and Alcohols

A. Beltrán, E. Álvarez, M.M. Díaz-Requejo, P. J. Pérez

Adv. Synth. Catal. 2015, 357, 2821-2826

 

 

 

103. Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of O-H Bonds

A. Pereira, Y. Champouret, C. Martin, E. Alvarez, M. Etienne, T. R. Belderrain, P. J. Pérez

Chem. Eur. J. 2015, 21, 9769-9775.

 

 

102. Copper-catalysed azide-alkyne cycloadditions (CuAAC): an update

E. Haldón, M. C. Nicasio, P. J. Pérez

Org. Biomol. Chem. 2015, 13, 9528-9550.

 

 

 

101. Discovering Copper for Methane C-H Bond Functionalization

R. Gava, A. Olmos, B. Noverges, T. Varea, E. Alvarez, T.R. Belderrain, A. Caballero, G. Asensio, P. J. Pérez

ACS Catalysis 2015, 5, 3726-3730.

 

 

100. A computational view on the reactions of hydrocarbons with coinage metal complexes

M. Besora, A. A. C. Braga, W. M. C. Sameera, J. Urbano, M.  R. Fructos, P. J. Pérez, F. Maseras

J. Organomet. Chem. 2015, 784, 2-12

 

 

 

99. Chiral, Sterically Demanding N-Heterocyclic Carbenes Fused into a Heterobiaryl Skeleton: Design, Synthesis, and Structural Analysis.

M. Espina, I. Rivilla, A. Conde, M. M. Díaz-Requejo, P. J. Pérez, E. Álvarez, R. Fernández, J. M. Lassaletta

Organometallics 2015, 34, 1328-1338.

 

 

 

 

 

98. A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow

L. Maestre, E. Ozkal, C. Ayats, A. Beltrán, M. M. Díaz-Requejo, P. J. Pérez, M. A. Pericàs

Chem. Sci. 2015, 6, 1510.

 

 

 

2014

 

97. Catalytic Copper-Mediated Ring Opening and Functionalization of Benzoxazoles

M. Corro, M. Besora, C. Maya, E. Álvarez, J. Urbano, M. R. Fructos, F. Maseras, P. J. Pérez

ACS Catalysis 2014, 4, 4215

 

 

 

96. Catalytic Functionalization of Methane and Light Alkanes in Supercritical Carbon Dioxide

M. A. Fuentes, A. Olmos, B. K. Muñoz, K. Jacob, E. González-Núñez, R. Mello, G. Asensio, A. Caballero, M. Etienne, P.J. Pérez

Chem. Eur. J. 2014, 20, 11013

 

 

95. 1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

E. Haldón, E. Álvarez, M. C. Nicasio, P. J. Pérez

Chem. Commun. 2014, 50, 8978

 

 

94. Silver-Catalyzed Functionalization of Esters by Carbene Transfer: The Role of Ylide Zwitterionic Intermediates

R. Gava, M. A. Fuentes, M. Besora, T. R. Belderrain, K. Jacob, F. Maseras, M. Etienne, A. Caballero, P. J. Pérez

ChemCatChem 2014, 6, 2206

 

 

93. Catalytic Functionalization of Indoles by Copper-Mediated Carbene Transfer

M. Delgado-Rebollo, A. Prieto, P. J. Pérez

ChemCatChem 2014, 6, 2047

 

 

92. Syntheses of a Novel Fluorinated Trisphosphinoborate Ligand and Its Copper and Silver Complexes. Catalytic Activity toward Nitrene Transfer Reactions

I. Arenas, M. A. Fuentes, E. Álvarez, Y. Díaz, A. Caballero, S. Castillón, P. J. Pérez

Inorg. Chem. 2014, 53, 3391

 

 

91. Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper(I) Complexes with a Series of Tetradentate Tripodal Tris(pyrazolylmethyl)amine Ligands

E. Haldón, M. Delgado-Rebollo, A. Prieto, E. Álvarez, C. Maya, M. C. Nicasio, P. J. Pérez

Inorg. Chem. 2014, 53, 4192.

 

 

 

90. Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions

J. Llaveria, A. Beltrán, W. M. C. Sameera, A. Locati, M. M. Díaz-Requejo, M. I. Matheu, S. Castillón, F. Maseras, P. J. Pérez

J. Am. Chem. Soc. 2014, 136, 5342.

 

 

 

89. Reaction of Alkynes and Azides: Not Triazoles Through Copper-Acetylides but Oxazoles Through Copper-Nitrene Intermediates

E. Haldón, M. Besora, I. Cano, X. C. Cambeiro, M.A. Pericas, F. Maseras, M. C. Nicasio, P. J. Pérez

Chem. Eur. J. 2014, 20, 3463.

 

 

 

2013

 

88. Supercritical Carbon Dioxide: A Promoter of Carbon-Halogen Bond Heterolysis

T. Delgado-Abad, J. Martinez-Ferrer, A. Caballero, A. Olmos, R. Mello, M. E. González-Núñez, P. J. Pérez, G. Asensio

Angew. Chem. Int. Ed. 2013, 52, 13298.

 

 

 

87. An Effective Dual Copper- and Sulfide-Catalytic System for the Epoxidation of Aldehydes with Phenyldiazomethane

A. Pereira, C. Martin, C. Maya, T. R. Belderrain, P. J. Pérez

Adv. Synth. Cat. 2013, 355, 2942.

 

 

 

86. Catalytic C-H amination of alkanes with sulfonimidamides: silver(I)-scorpionates vs. dirhodium(II) carboxylates

A. Beltrán, C. Lescot, M. M. Díaz-Requejo, P. J. Pérez, P. Dauban

Tetrahedron 2013, 69, 4428.

 

 

 

85. Introducing Copper as Catalyst for Oxidative Alkane Dehydrogenation

A. Conde, L. Vilella, D. Balcells, M. M. Díaz-Requejo, A. Lledós, P. J. Pérez

J. Am. Chem. Soc. 2013, 135, 3887.

 

 

 

 

84. A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

L. Maestre, W. M. C. Sameera, M. M. Díaz-Requejo, F. Maseras, P. J. Pérez

J. Am. Chem. Soc. 2013, 135, 1338.

 

 

83. Methane as raw material in synthetic chemistry: the final frontier

A. Caballero, P. J. Pérez

Chem. Soc. Rev. 2013, 42, 8809

 

 

82. Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study

I. Rivilla, W. M. C. Sameera, E. Álvarez, M. M. Díaz-Requejo, F. Maseras, P. J. Pérez

Dalton Trans. 2013, 42, 4132

 

 

 

 

81. Functionalization of Non-activated C-H Bonds of Alkanes: An Effective and Recyclable Catalytic System Based on Fluorinated Silver Catalysts and Solvents

M. A. Fuentes, B. K. Muñoz, K. Jacob, L. Vendier, A. Caballero, M. Etienne, P. J. Pérez

Chem. Eur. J. 2013, 19, 1327.

 

 

80. Silver-catalyzed silicon-hydrogen bond functionalization by carbene insertion

M. J. Iglesias, M. C. Nicasio, A. Caballero, P.J. Pérez

Dalton. Trans. 2013, 42, 1191.

 

 

 

2012

 

79. Mild Catalytic Functionalization of Styrene-Butadiene Rubbers

A. Beltrán, B. P. Gómez-Emeterio, C. Marco, G. Ellis, M.D. Parellada, M. M. Díaz-Requejo, S. Corona-Galván, P. J. Pérez

Macromolecules 2012, 45, 9267.

 

 

 

78. Copper-Catalyzed Nitrene Transfer as a Tool for the Synthesis of N-Substituted 1,2-Dihydro- and 1,2,3,4-Tetrahydropyridines

L. Maestre, M. R. Fructos, M. M. Díaz-Requejo, P.J. Pérez

Organometallics 2012, 31, 7839.

 

 

 

77. Copper(I) Complexes with Trispyrazolylmethane Ligands: Synthesis, Characterization, and Catalytic Activity in Cross-Coupling Reactions

E. Haldón, E. Álvarez, M. C. Nicasio, P. J. Pérez

Inorg. Chem. 2012, 15, 8298

 

 

 

76. Catalytic Hydrocarbon Functionalization with Gold Complexes Containing N-Heterocyclic Carbene Ligands with Pendant Donor Groups

M. Delgado-Rebollo, A. Beltrán, A. Prieto, M. M. Díaz-Requejo, A. M. Echavarren, P. J. Pérez

Eur. J. Inorg.Chem. 2012, 9, 1380.

 

 

 

75. Polynuclear Copper(I) Complexes with Chelating Bis- and Tris-N-Heterocyclic Carbene Ligands: Catalytic Activity in Nitrene and Carbene Transfer Reactions

C. Tubaro, A. Biffis, R. Gava, E. Scattolin, A. Volpe, M. Basato, M. M. Díaz-Requejo, P. J. Pérez

Eur. J. Org.Chem. 2012, 7, 1367.

 

 

74. [(PhBP3)Cu(PPh3)] as a Surrogate of TpxCuL in Homogeneous Catalysis (PhBP3 = PhB(CH2PPh2)3; Tpx = Hydrotrispyrazolylborate)

M. A. Fuentes, E. Álvarez, A. Caballero, P.J. Pérez

Organometallics 2012, 31, 959.

 

 

73. Cu(I)-catalyzed atom transfer radical cyclization of trichloroacetamides tethered to electron-deficient, -neutral, and -rich alkenes: synthesis of polyfunctionalized 2-azabicyclo[3.3.1]nonanes

F. Diaba, A. Martinez-Laporta, J. Bonjoch, A. Pereira, J. M. Muñoz-Molina, P. J. Pérez, T. R. Belderrain

Chem. Commun. 2012, 48, 8799

 

 

 

72. Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl - experimental and DFT computational study

A.P. Kadina, A. F. Khlebnikov, M. S. Novikov, P.J. Pérez, D. S. Yufit

Org. Biomol. Chem. 2012, 10, 5582.

 

 

71. Hydrotris(3-mesitylpyrazolyl)borato-copper(I) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalyst

C. Martin, M. Sierra, E. Álvarez, T. R. Belderrain, P. J. Pérez

Dalton Trans. 2012, 41, 5319.

 

 

2011

 

70. Mechanism of Side Reactions in Alkane C-H Bond Functionalization by Diazo Compounds Catalyzed by Ag and Cu Homoscorpionate Complexes-A DFT Study

A. A: C. Braga, A. Caballero, J. Urbano, M. M. Díaz-Requejo, P.J. Pérez, F. Maseras

ChemCatChem 2011, 3, 1646.

 

 

69. Atom Transfer Radical Reactions as a Tool for Olefin Functionalization - On the Way to Practical Applications

J. M. Muñoz-Molina, T. R. Belderrain, P. J. Pérez

Eur. J. Inorg. Chem. 2011, 21, 3155.

 

 

68. Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts

I. Rivilla, B.P. Gómez-Emeterio, M.R. Fructos, M. M. Díaz-Requejo, P. J. Pérez

Organometallics 2011, 30, 2855

 

 

67. Gold-catalyzed naphthalene functionalization

P. J.Pérez, M. M. Díaz-Requejo, I.Rivilla

Bielstein J. Org. Chem. 2011, 7, 653.

 

 

66. Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

A. Caballero, E. Despagnet-Ayoub, M. M. Díaz-Requejo, A. Díaz-Rodríguez, M. E. González-Núñez, R. Mello, B. K. Muñoz, W. Solo Ojo, G. Asensio, M. Etienne, P. J. Pérez

Science 2011, 332, 835

 

 

 

65. Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: gold as a spectator

M. A. Fuentes, M. Rodríguez-Castillo, M, Monge, M. E. Olmos, J. M. López-de-Luzuriaga, A. Caballero, P. J. Pérez

Inorg. Chim. Acta 2011, 369, 146.

 

 

 

64. Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes

J. M. Muñoz-Molina, W. M. C. Sameera, E. Álvarez, F. Maseras, T. R. Belderrain, P. J. Pérez

Inorg. Chem. 2011, 50, 2458

 

 

 

63. Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes

I. Cano, E. Alvarez, M. C. Nicasio, P. J. Pérez

J. Am. Chem Soc. 2011, 133, 191

 

 

62. Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions

A. Conde, M. M. Díaz-Requejo, P. J. Pérez

Chem. Commun. 2011, 47, 8154.

 

 

2010

 

61. Copper(I)-Olefin Complexes: The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity

C. Martín, J. M. Muñoz-Molina, A. Locati, E. Alvarez,F. Maseras, T. R. Belderrain and P. J. Pérez

Organometallics 2010, 29, 3481

 

60. Catalytic Cyclopropanation of Polybutadienes

J. Urbano, B. Khorthals, M. M. Díaz-Requejo, P. J. Pérez, S. Mecking

J. Pol. Sci. A.: Pol. Chem. 2010, 48, 4439

 

 

59. Efficient Silver-Catalyzed Regio- and Stereospecific Aziridination of Dienes

J. Llaveria, A. Beltrán, M. M. Díaz-Requejo, M. I. Matheu, S. Castillón, and P. J. Pérez

Angew. Chem. Int Ed. 2010, 49, 7092.

 

 

 

58. Efficient Atom-Transfer Radical Polymerization of Methacrylates Catalyzed by Neutral Copper Complexes

J. M. Muñoz-Molina, T. R. Belderrain, P. J. Pérez

Macromolecules 2010, 43, 3221

 

 

57. Selective Synthesis of N-Substituted 1,2-Dihydropyridines from Furans by Copper-Induced Concurrent Tandem Catalysis

M. R: Fructos, E. Álvarez, M. M. Díaz-Requejo, P. J. Pérez

J. Am. Chem Soc. 2010, 132, 4600

 

 

56. An Efficient, Selective and Reducing Agent-Free Copper-Catalyst for the Atom-Transfer Radical Addition of Halo-Compounds to Activated Olefins

J. M. Muñoz-Molina, T. R. Belderrain, P. J. Pérez

Inorg. Chem. 2010, 49, 642

 

 

 

55. Copper(I) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes

I. Cano, M. C. Nicasio, P. J. Pérez

Org. Biomol. Chem. 2010,8, 536.

 

 

 

2009

 

54. Hydrotrispyrazolylborate-copper complexes as catalysts for the styrene cyclopropanation reaction with ethyl diazoacetate under homogeneous and heterogeneous conditions

A. Caballero, M. Sabater, M. E. Morilla, M. C. Nicasio, T. R. Belderraín, M. M. Díaz-Requejo, P. J. Pérez

Inorg. Chim. Acta 2009, 362, 4599 (THEMATIC ISSUE: Protagonists in Chemistry: Swiatoslaw Trofimenko)

 

 

53. Gold-catalyzed olefin cyclopropanation

A. Prieto, M. R. Fructos, M. M. Díaz-Requejo, P. J. Pérez, P. Pérez-Galán, N. Delpont, A. M. Echavarren

Tetrahedron 2009, 65, 1790 (THEMATIC ISSUE: RECENT DEVELOPMENTS IN GOLD CATALYSIS)

 

 

52. Metal-Catalyzed Olefin Cyclopropanation with Ethyl Diazoacetate: Control of the Diastereoselectivity

A. Caballero, A. Prieto, M. M. Díaz-Requejo, Pedro J. Pérez

Eur. J. Inorg. Chem. 2009, 1137 (MICROREVIEW)

 

 

51. The Mechanism of the Catalytic Functionalization of Haloalkanes by Carbene Insertion: An Experimental and Theoretical Study

J. Urbano, A. A. C. Braga, F. Maseras, E. Álvarez, M. M. Díaz-Requejo, P. J. Pérez

Organometallics 2009, 28, 5968

 

 

50. Rediscovering copper-based catalysts for the intramolecular carbon-hydrogen bond functionalization by carbene insertion

C. Martín, T. R. Belderraín, P. J. Pérez

Org. Biomol. Chem. 2009, 7, 4777

 

 

49. Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate

M. R. Fructos, M. M. Díaz-Requejo, P. J. Pérez

Chem Commun 2009, 28, 5153

 

 

48. Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions

E. Haldón, E. Álvarez, M. C. Nicasio, P. J. Pérez

Organometallics 2009, 28, 3815

 

 

47. Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

I. Cano, M. C. Nicasio, P. J. Pérez

Dalton Trans 2009, 28, 730

 

 

 

46. Asymmetric b-Boration of a,b-Unsaturated Esters with Chiral (NHC)Cu Catalysts

V.Lillo, A. Prieto, A. Bonet, M. M. Díaz-Requejo, J. Ramírez, P. J. Pérez, E. Fernández

Organometallics 2009, 28, 659

 

 

 

2008

 

45. Copper-Catalyzed Synthesis of 1,2-Disubstituted Cyclopentanes from 1,6-Dienes by Ring-Closing Kharasch Addition of Carbon Tetrachloride

J. M. Muñoz-Molina, T. R. Belderrain, P. J. Pérez

Adv. Synth. Catal. 2008, 350, 2365

 

 

 

44. Coinage Metal Catalyzed C-H Bond Functionalization of Hydrocarbons

M. M. Díaz-Requejo and P. J. Pérez

Chem. Rev. 2008, 108, 3379. (COINAGE METAL THEMATIC ISSUE)

 

 

43. A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)

E. Despagnet-Ayoub, K. Jacob, L. Vendier, M. Etienne, E. Alvarez, A. Caballero, M. M. Díaz-Requejo, and P. J. Pérez

Organometallics 2008, 27, 4779.

 

 

42. Easy Alkane Catalytic Functionalization

B. P. Gómez-Emeterio, J. Urbano, M. M. Díaz-Requejo, and P. J. Pérez

Organometallics 2008, 27, 4126.

 

 

41. Gold -promoted Styrene Polymerization

J. Urbano, A. J. Hormigo, P.de Frémont, S. P. Nolan, M. M. Díaz-Requejo and P. J. Pérez

Chem. Commun. 2008 , 759

 

 

2007

 

40. Catalytic Carbon-Hydrogen Bond Functionalization in an Ionic Liquid Medium

P. Rodríguez, E. Alvarez, M. C. Nicasio, P. J. Pérez

Organometallics 2007, 26, 6661.

 

 

39. Synthesis, characterization and reactivity of ruthenium diene/diamine complexes including catalytic hydrogenation of ketones

M. E. Morilla, P. Rodríguez, T. R. Belderrain, C. Graiff, A. Tiripicchio, M. C. Nicasio, P. J. Pérez

Inorg. Chem. 2007, 46, 9405

 

 

38. Homoscorpionate Complexes as Active Catalysts for Atom Transfer Radical Addition to Olefins

J. M. Muñoz-Molina, A. Caballero, M. M. Díaz-Requejo, S. Trofimenko, T. Belderrain and P.J. Pérez

Inorg. Chem. 2007, 46, 7725

 

 

37. Effects of the Substituents in the TpxCu Activation of Dioxygen: An Experimental Study

M. A. Mairena, J. Urbano, J. Carbajo, J. J. Maraver, E. Alvarez, M. M. Díaz-Requejo and P.J. Pérez

Inorg. Chem. 2007, 46, 7428

 

 

36. Effect of the Catalyst Loading in the Copper- Catalyzed Cyclohexane Functionalization by Carbene Insertion.

A. Caballero, M. M. Díaz-Requejo, S. Trofimenko, Tomás R. Belderrain and P. J. Pérez

Eur. J. Inorg. Chem. 2007, 2848.

 

 

35. Unusual Polybrominated Polypyrazolylborates and Their Copper(I) Complexes: Synthesis, Characterization and Catalytic Activity.

G. P. A. Yap, F. Joves, J. Urbano, E. Alvarez, S. Trofimenko, M. M. Díaz-Requejo and P.J. Pérez

Inorg. Chem. 2007, 46, 780.

 

 

34. A Valuable, Inexpensive (NHC)Cu(I) Catalyst for the Selective Diboration of Unsaturated C-C.

V. Lillo, M. R. Fructos, J. Ramirez, M. M. Díaz-Requejo, P.J. Pérez and E. Fernández

Chemistry A European Journal 2007, 13, 2614.

 

 

 

2006

 

 

33. The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: No classical C-H activation, but efficient C-H functionalization.

M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio and P. J. Pérez.

Dalton Trans 2006, 5559-5566 (Perspective)

 

 

32. Mechanism of Alkane C-H Bond Activation by Copper and Silver Homoscorpionate Complexes.

A. A. C. Braga, F. Maseras, J. Urbano, A. Caballero, M. M. Díaz-Requejo, P. J. Pérez.

Organometallics 2006, 25, 5292-5300.

 

 

31. Facile Amine Formation by Intermolecular Catalytic Amidation of Carbon-Hydrogen Bonds.

M. R. Fructos, S. Trofimenko, M. M. Díaz-Requejo, P.J. Pérez.

J. Am. Chem. Soc. 2006, 128, 11784-11791.

 

 

30. Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes.

P. de Fremont, E. D. Stevens, M. R. Fructos, M. M. Diaz-Requejo, P. J. Pérez, S. P. Nolan

Chem Commun 2006, 2045-2047

 

 

29. Non-Fluorous Copper-Catalyst for the Styrene Cyclopropanation reaction in a Fluorous Medium.

J. Urbano, S. Trofimenko, M. M. Díaz-Requejo, P.J. Pérez

Chem Commun 2006, 1000-1002.

 

 

 

28. A Very Efficient Reusable Copper Catalyst for Carbene Transfer Reactions under Biphasic Conditions using Ionic Liquids.

P. Rodríguez, A. Caballero, M. M. Díaz-Requejo, M. C. Nicasio and P. J. Pérez

Org. Lett. 2006, 8, 557-560.

 

 

27. Alkane Carbon-Hydrogen Bond Functionalization with (NHC)MCl Pre-catalysts.

(M = Cu, Au; NHC = N-Heterocyclic Carbene).

M. R. Fructos, P. de Frémont, S. P. Nolan, M. M. Díaz-Requejo, P. J. Pérez

Organometallic 2006, 25, 2237-2241

 

 

2005

 

26. Copper, Silver and Gold-Based Catalysts for Carbene Addition or Insertion Reactions

M. Mar Díaz-Requejo, Pedro J. Pérez

J. Organomet. Chem. 2005, 690, 5441-5450.

 

 

25. A Gold Catalyst for Carbene Transfer Reactions from Ethyl Diazoacetate.

M. R. Fructos, T. R. Belderrain, P. de Frémont, N. M. Scout, S. P. Nolan, M. M. Díaz-Requejo, P.J. Pérez

Angew. Chem. Int. Ed. 2005, 44, 5284-5288.

 

 

24. Copper-Catalyzed Addition of Ethyl Diazoacetate to Furans: An Alternative to Rhodium Tetraacetate.

A. Caballero, M. M. Díaz-Requejo, M. C. Nicasio, S. Trofimenko, T. R. Belderrain and P. J. Pérez

J. Org. Chem. 2005, 70, 6101-6104.

 

 

23. Controlled, Copper-Catalyzed Functionalization of Polyolefins.

M. M. Díaz-Requejo, P. Wehrmann, M. D. Leatherman, S. Trofimenko, S. Mecking, M. Brookhart, P.J. Pérez.

Macromolecules 2005, 38, 4966-4969

 

 

22. Functionalization of primary carbon-hydrogen bonds of alkanes by carbene insertion with a silver-based catalyst.

J. Urbano , T. R. Belderrain, M. C. Nicasio, S. Trofimenko, M. M. Díaz-Requejo, P.J. Pérez.

Organometallics 2005, 24, 1528-1532.

 

 

2004

 

21. Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate: a (NHC)-Cu System that Suppresses Diazo Coupling (NHC = N-Heterocyclic Carbene).

M. R. Fructos , T. R. Belderrain, M. C. Nicasio, S. Trofimenko, M. M. Díaz-Requejo, P.J. Pérez.

J. Am. Chem. Soc. 2004, 126, 10846-10847.

 

 

20. Alkane Dehydrogenation by Sequential, Double C-H Bond Activation with an Ir(I)-Homoscorpionate Complex.

P. Rodríguez.; M. M. Díaz-Requejo, T. R. Belderrain,, S. Trofimenko M. C. Nicasio, P.J. Pérez.

Organometallics 2004, 23, 2162-2167.

 

 

19. Copper-Homoscorpionate Complexes as Very Active Catalysts for the Olefin Aziridination Reaction.

M. A. Mairena, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez

Organometallics 2004, 23, 253-256.

 

 

 

18. Reaction of ethyldiazoacetate with alkyl-aromatic substrates: Influence of the TpxCu catalyst in the addition vs. insertion chemoselectivity (Tpx = homoscorpionate).

M. E. Morilla, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez

Organometallics 2004, 23, 293-295.

 

 

2003

 

17. Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C-H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe).

M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez.

J. Am. Chem. Soc. 2003, 125, 12078-12079.

 

 

16. Functionalization of Carbon-Hydrogen Bond of Hydrocarbonds and Ethers vía Carbene Insertion: Control of the Regioselectivity by Copper(I)-Homoscorpionate Catalysts.

A. Caballero, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez.

Organometallics 2003, 22, 4145-4150.

 

 

15. Copper-Catalysts Carbene Insertion into O-H Bond: High Selectivity Conversion of Alcohols into Ethers.

M. E. Morilla, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez

Organometallics 2003, 22, 2914-2918.

 

 

 

 

14. Highly Regioselective Functionalization of Aliphatic Carbon-Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst.

A. Caballero, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez.

J. Am. Chem. Soc. 2003, 125, 1446-1447.

 

 

2002

 

13. Catalytic insertion of diazo compounds into N-H bonds: the copper alternative.

M. E. Morilla, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P.J. Pérez

Chem. Commun 2002, 2998-2999.

 

 

12. Intermolecular dealkylation of chelating diamines with Ru(II) amines.

M. E. Morilla, G. Morfes, M. C. Nicasio, T. R. Belderrain, M. M. Díaz-Requejo, C. Graiff,

A. Tiripiccio, R. Sánchez-Delgado, P. J. Pérez.

Chem. Commun. 2002, 1848-1849.

 

 

11. Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis-cyclopropanation of a-olefins with ethyldiazoacetate.

M. M. Díaz-Requejo, A. Caballero, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P. J. Pérez

J. Am. Chem. Soc. 2002, 124, 978-983.

 

 

10. Copper-Catalyzed Carbon-Hydrogen Bond Activation via Carbene Insertion

M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P. J. Pérez

J. Am. Chem. Soc. 2002, 124, 896-897.

 

 

2001

 

9. A family of highly active copper(I)-homoscorpionate catalysts for the alkyne

cyclopropenation reaction.

M.M. Díaz-Requejo, M. A. Mairena, T. R. Belderrain, M. C. Nicasio, S. Trofimenko, P. J. Pérez

Chem. Commun. 2001, 1804-1805.

 

8. Unprecedented Highly cis-Diastereoselective Olefin Cyclopropanation Using Copper Homoscorpionate Catalysts

M. M. Díaz-Requejo, T. R. Belderrain, S. Trofimenko, P. J. Pérez

J. Am. Chem. Soc. 2001, 123, 3167-3168.

 

 

7. The Use of Polypyrazolylborate Copper(I) Complexes as Catalysts in the Conversion of Olefins into Cyclopropanes, Aziridines and Epoxides and Alkynes into Cyclopropenes.

M. M. Díaz-Requejo, P. J. Pérez

J. Organomet. Chem. 2001, 617, 110-118.

 

 

2000

 

6. Polypyrazolylborate copper(I) complexes as catalysts of the homogeneous and heterogeneous styrene epoxidation reaction.

M.M. Díaz-Requejo, T. R. Belderrain, S. Trofimenko, P. J. Pérez

Chem. Commun. 2000, 1853-1854

 

 

5. Novel(Methyl)- and-(Acetyl)palladium Complexes Containing Bis(pyrazolyl)borate Ligands –Dynamic Equilibrium between h2 and h1 Forms for the Complex Bp*(Me)(PCy3)Pd [Bp* = dihydrobis(3,5-dimethylpyrazolyl)borate].

M. M. Díaz-Requejo, M. C. Nicasio, T. R. Belderrain, P. J. Pérez, M. C. Puerta, P. Valerga

Eur. J. Inorg. Chem. 2000, 1359-1364.

 

 

4. From Homogeneous to Heterogeneous Catalysis: Novel Anchoring of Polypyrazolylborate Copper(I) Complexes on Silica Gel Through Classical and Nonclassical Hydrogen Bonds. Use as Catalysts of the Olefin Cyclopropanation Reaction.

M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, P. J. Pérez

Organometallics 2000, 19, 285-289.

 

 

1999

 

3. Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp=Dihydrobis(pyrazolyl)borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated Olefin Cyclopropanation?

M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, F. Prieto, P. J. Pérez

Organometallics 1999, 18, 2601-2609.

 

 

 

1998

 

2. BpCu-Catalyzed Cyclopropanation of Olefins: A Simple System that Operates under Homogeneous and Heterogeneous Conditions (Bp = Dihydrobis(pyrazolyl)borate)

M. M. Díaz-Requejo, M. C. Nicasio, P. J. Pérez

Organometallics 1998, 17, 3051-3057.

 

 

1997

 

1. Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para-Substituted Styrenes

M. M. Díaz-Requejo, P. J. Pérez, M. Brookhart, J.L.Templeton

Organometallics 1997, 16, 4399-4402.

 

 

 

 

 

 

 

Articles not including P. J. Pérez

 

Phototransformation of benzimidazole and thiabendazole inside cucurbit[8]uril

J. Smitka, A. Lemos, M. Porel, S. Jockusch, T. R. Belderrain, E. Tesarova, J.P. Da Silva

Photochem. Photobio. Sci. 2014, 13, 210

 

Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium

Z. D. Miller, W. Li, T. R. Belderrain, J. Montgomery

J. Am. Chem. Soc. 2013, 135, 15282.

 

Gold-catalyzed Mannich addition reactions of 1,3-dicarbonyl compounds with N-protected imines

M. Delgado-Rebollo, R. Moreno, M. R. Fructos, A. Prieto

Eur. J. Org. Chem. 2013, 31

 

Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)(2) in the Amination of Aryl Tosylates

M. J. Iglesias, J. F. Blández, M. R. Fructos, A. Prieto, E. Álvarez, T. R. Belderrain, M. C. Nicasio

Organometallics 2012, 31, 6312.

 

Kumada-Tamao-Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

M. J. Iglesias, A. Prieto, M. C. Nicasio

Org. Lett. 2012, 14, 4318.

 

Stable N-Heterocyclic Carbene (NHC)-Palladium(0) Complexes as Active Catalysts for Olefin Cyclopropanation Reactions with Ethyl Diazoacetate

C. Martin, F. Molina, E. Álvarez, T. R. Belderrain

Chem. Eur. J. 2011, 17, 14885.

 

Well-Defined Allylnickel Chloride/N-Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for C-N and C-S Cross-Coupling Reactions

M. J. Iglesias, A. Prieto, M. C. Nicasio

Adv. Synth. Cat. 2010, 352, 1949.

 

The selective catalytic formation of β-boryl aldehydes through a base-free approach

A. Bonet, V. Lillo, J. Ramírez, M. M. Díaz-Requejo, E. Fernández

Org. Biomol. Chem. 2009, 7, 1533.

 

C-N Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor

S. G. Rull, J.F. Blández, M. R. Fructos, T. R. Belderrain, M. C. Nicasio

Adv. Synth. Cat. 2015, 357, 907-911.

 

Centro de Investigación en Química Sostenible (CIQSO)

Edificio Robert H Grubbs, Campus de El Carmen

Universidad de Huelva

21007 Huelva