Publicaciones

Unidad DE MINERALOGÍA Y GEOQUÍMICA AMBIENTAL

Menú laboratorio

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Publicaciones más relevantes del Grupo (desde 2015):

2024

1. León R, Macías F, Cánovas CR, Millán R, Romero J & Nieto JM (2024). Origin of rare earth elements in acid mine drainage traced by strontium and neodymium isotopes. Geochimica et Cosmochimica Acta 372, 101-110. https://doi.org/10.1016/j.gca.2024.03.025

2. Millán-Becerro R, León R, Romero J, Moreno R & Pérez-López R (2024). Towards circular and sustainable restoration of a deeply polluted river basin: The Odiel River catchment (SW Spain). Science of The Total Environment 907, 168078. https://doi.org/10.1016/j.scitotenv.2023.168078

2023

1. Basallote MD, Zarco V, Macías F, Cánovas CR & Hidalgo P (2023). Metal bioaccumulation in spontaneously grown aquatic macrophytes in Fe-rich substrates of a passive treatment plant for acid mine drainage. Journal of Environmental Management 345, 118495. https://doi.org/10.1016/j.jenvman.2023.118495 .

2. Bilal E, Bellefqih H, Bourgier V, Mazouz H, Dumitraş D, Bard F, Laborde M, Caspar JP, Guilhot B, Iatan L, Bounakhla M, Iancu MA, Marincea Ş, Essakhraoui M, Li B, Diwa R, Ramirez JD, Chernysh Y, Chubur V, Roubík H, Schmidt H, Beniazza R, Cánovas CR, Nieto JM & Haneklaus N (2023). Phosphogypsum circular economy considerations: A critical review from more than 65 storage sites worldwide. Journal of Cleaner Production 414, 137561. https://doi.org/10.1016/j.jclepro.2023.137561

3. Cánovas CR, Moreno R, Vieira BJC, Waerenborgh JC, Marques R, Macías F, Basallote MD, Olías M & Prudencio MI (2023). Metal mobility and bioaccessibility from cyanide leaching heaps in a historical mine site. Journal of Hazardous Materials 448, 130948. https://doi.org/10.1016/j.jhazmat.2023.130948

4. Cánovas CR, Quispe D, Macías F, Callejón B, Arias A, García-Barrera T & Nieto JM (2023). Potential release and bioaccessibility of metal/loids from mine wastes deposited in historical abandoned sulfide mines. Environmental Pollution 316, 120629. https://doi.org/10.1016/j.envpol.2022.120629

5. Cuadros J, Mavris C & Nieto JM (2023). Rare earth element signature modifications induced by differential acid alteration of rocks in the Iberian Pyrite Belt. Chemical Geology 619, 121323. https://doi.org/10.1016/j.chemgeo.2023.121323

6. Guerrero JL, Suárez-Vaz N, Paz-Gómez DC, Pérez-Moreno SM & Bolívar JP (2023). Spatiotemporal evolution of U and Th isotopes in a mine effluent highly polluted by Acid Mine Drainage (AMD). Journal of Hazardous Materials 447, 130782. https://doi.org/10.1016/j.jhazmat.2023.130782

7. Kerl CF, Basallote MD, Käberich M, Oldani E, Cerón NP, Colina AE, Cánovas CR, Nieto JM & Planer-Friedrich B (2023). Consequences of sea level rise for high metal(loid) loads in the Ría of Huelva estuary sediments. Science of the Total Environment 873, 162354. https://doi.org/10.1016/j.scitotenv.2023.162354

8. Kotte-Hewa DJ, Durce D, Salah S, Cánovas CR & Smolders E (2023). Remediation of acid mine drainage and immobilization of rare earth elements: Comparison between natural and residual alkaline materials. Applied Geochemistry 158, 105800. https://doi.org/10.1016/j.apgeochem.2023.105800

9. León R, Macías F, Cánovas CR, Millán-Becerro R, Pérez-López R, Ayora C & Nieto JM (2023). Evidence of rare earth elements origin in acid mine drainage from the Iberian Pyrite Belt (SW Spain). Ore Geology Reviews, 154, 105336. https://doi.org/10.1016/j.oregeorev.2023.105336

10. Millán-Becerro R, Cánovas CR, Macías F, Roetting T, Siddorn L, Stanley P & Nieto JM (2023). Passive remediation of mine waters from Parys Mountain (Wales): Laboratory column experiments. Journal of Cleaner Production 425, 138872. https://doi.org/10.1016/j.jclepro.2023.138872

11. Millán-Becerro R, Pérez-López R, Cánovas CR, Macías F & León R (2023). Phosphogypsum weathering and implications for pollutant discharge into an estuary. Journal of Hydrology 617A, 128943. https://doi.org/10.1016/j.jhydrol.2022.128943

12. Moreno R, Cánovas CR, Millán-Becerro R, León R & Olías M (2023). High-resolution temporal monitoring of rare earth elements in acidic drainages from an abandoned sulphide mine (Iberian Pyrite Belt, Spain). Chemosphere 344, 140297. https://doi.org/10.1016/j.chemosphere.2023.140297

13. Moreno R, Macías F, Meyer A, Schneider P, Nieto JM, Olías M & Cánovas CR (2023). Life cycle assessment of management/valorisation practices for metal-sludge from treatment of acid mine drainage. Environmental Impact Assessment Review 99, 107038. https://doi.org/10.1016/j.eiar.2023.107038

14. Olías M, Cánovas CR, Basallote MD, Macías F, Nieto JM, Pérez-López R & Sarmiento AM (2023). El problema del drenaje ácido de minas en la Faja Pirítica Ibérica. Diagnóstico y medidas de tratamiento. Servicio de Publicaciones, Universidad de Huelva (ISBN 978-84-19397-79-9), 200 pp. https://www.uhu.es/publicaciones/?q=libros&code=1322

15. Packman H, Little SH, Nieto JM, Basallote MD, Pérez-López R, Coles B, Kreissig K, van de Flierdt T & Rehkämper M. (2023). Tracing acid mine drainage and estuarine Zn attenuation using Cd and Zn isotopes. Geochimica et Cosmochimica Acta 360, 36-56. https://doi.org/10.1016/j.gca.2023.09.001

16. Pérez-López R, Millán-Becerro R, Basallote MD, Carrero S, Parviainen A, Freydier R, Macías F & Cánovas CR. (2023). Effects of estuarine water mixing on the mobility of trace elements in acid mine drainage leachates. Marine Pollution Bulletin 187, 114491, 1-10. https://doi.org/10.1016/j.marpolbul.2022.114491

17. Romero-Matos J, Cánovas CR, Macías F, Pérez-López R, León R, Millán-Becerro R & Nieto JM. (2023). Wildfire effects on the hydrogeochemistry of a river severely polluted by acid mine drainage. Water Research 233, 119791. https://doi.org/10.1016/j.watres.2023.119791

2022

1. Ayora C, Carrero S, Bellés J, Basallote MD, Cánovas CR & Macías F (2022). Partition of rare earth elements between sulfate salts formed by the evaporation of acid mine drainage. Mine Water and the Environment 41, 42-57. https://doi.org/10.1007/s10230-021-00803-0

2. Blasco J & Basallote MD (2022). Using chemical lines of evidence to address acidification. In: CO2 Acidification in Aquatic Ecosystems. An integrative approach to Risk Assessment (Eds: Del Valls TA & Riba I), 45-78. Elsevier, ISBN: 978-0-12-823552-2. https://doi.org/10.1016/B978-0-12-823552-2.00004-6

3. Cánovas CR, Basallote MD, Macías F, Freydier R, Parviainen A & Pérez-López R (2022). Thallium distribution in an estuary affected by acid mine drainage (AMD): The Ría de Huelva estuary (SW Spain). Environmental Pollution 306, 119448. https://doi.org/10.1016/j.envpol.2022.119448

4. Cánovas CR, Basallote MD, Macías F, Olías M, Pérez-López R & Nieto JM (2022). Thallium in environmental compartments affected by acid mine drainage (AMD) from the Iberian Pyrite Belt (IPB): from rocks to the ocean. Earth-Science Reviews 235, 104264. https://doi.org/10.1016/j.earscirev.2022.104264

5. Carrero S, Fernández-Martínez A, Pérez-López R, Cama J, Dejoie C & Nieto JM (2022). Effects of Aluminum Incorporation on Schwertmannite: Structure and Surface Properties. Environmental Science: Processes & Impacts. 24, 1383-1391 https://doi.org/10.1039/D2EM00029F

6. Fuentes-López JM, Olías M, León R, Basallote MD, Macías F, Moreno-González R & Cánovas CR (2022). Stream-pit lake interactions in an abandoned mining area affected by acid drainage (Iberian Pyrite Belt). Science of The Total Environment 833, 155224. https://doi.org/10.1016/j.scitotenv.2022.155224

7. Gómez-Arias A, Yesares L, Díaz J, Caraballo M, Maleke M, Sáez R, Van Heerden E, Vermeulen D, Nieto JM & Castillo J (2022). Mine waste from carbonatite deposits as potential rare earth resource: Insight into the Phalaborwa (Palabora) Complex. Journal of Geochemical Exploration 232, 106884. https://doi.org/10.1016/j.gexplo.2021.106884

8. Guillén MT, Delgado J, Gómez-Arias A, Nieto JM & Castillo J (2022). Bioaccessibility and human exposure to metals in urban soils (Huelva, SW Spain): evaluation by in vitro gastric extraction. Environmental Geochemistry and Health 44, 1501-1519. https://doi.org/10.1007/s10653-021-00814-4

9. Haneklaus N, Barbossa S, Basallote MD, Bertau M, Bilal E, Chajduk E, Chernysh Y, Chubur V, Cruz J, Dziarczykowski K, Fröhlich P, Grosseau P, Hamid M, Kiegiel K, Nieto JM, Pavón S, Pessanha S, Pryzowicz A, Roubík H, Cánovas CR, Schmidt H, Seeling R & Zakrzewska G (2022). Closing the upcoming EU gypsum gap with phosphogypsum. Resources, Conservation & Recycling 182, 106328. https://doi.org/10.1016/j.resconrec.2022.106328

10. Isgro M, Basallote MD & Barbero L (2022). Unmanned Aerial System-Based multispectral water quality monitoring in the Iberian Pyrite Belt (SW Spain). Mine Water and the Environment 41, 30-41. https://doi.org/10.1007/s10230-021-00837-4

11. Isgró MA, Basallote MD, Caballero I & Barbero L (2022). Comparison of UAS and Sentinel-2 Multispectral Imagery for Water Quality Monitoring: A Case Study for Acid Mine Drainage Affected Areas (SW Spain). Remote Sensing 14, 4053. https://doi.org/10.3390/rs14164053

12. Millán-Becerro R, Macías F, Cánovas CR, Pérez-López R & Fuentes-López JM (2022). Environmental management and potential valorization of wastes generated in passive treatments of fertilizer industry effluents. Chemosphere 295, 133876 https://doi.org/10.1016/j.chemosphere.2022.133876

13. Moreno R, Macías F, Olías M & Cánovas CR (2022). Temporal evolution of acid mine drainage (AMD) leachates from the abandoned Tharsis mine (Iberian Pyrite Belt, Spain). Environmental Pollution 295, 118697. https://doi.org/10.1016/j.envpol.2021.118697

14. Neira P, Romero-Freire A, Basallote MD, Qiu H, Cobelo-García A & Cánovas CR (2022). Review of the concentration, bioaccumulation, and effects of lanthanides in marine systems. Frontiers in Marine Science 9, 920405. https://doi.org/10.3389/fmars.2022.920405

15. Thomas R, Mantero J, Cánovas CR, Holm E, García-Tenorio R, Forssell-Aronsson E & lsakssone M (2022). Natural radioactivity and element characterization in pit lakes in Northern Sweden. PLoS ONE 17, e0266002. https://doi.org/10.1371/journal.pone.0266002

16. Villegas PG, Guerrero JL, Pérez-Rodríguez M, Bolívar JP, Morillo A, Vigara J & León R (2022). Exploring the microbial community inhabiting the phosphogypsum stacks of Huelva (SW SPAIN) by a high throughput 16S/18S rDNA sequencing approach. Aquatic Toxicology 245, 106103. https://doi.org/10.1016/j.aquatox.2022.106103

17. Villegas PG, Guerrero JL, Pérez-Rodríguez M, Bolívar JP, Vigara J & León R (2022). Metabarcoding data of prokaryotes and eukaryotes inhabiting the phosphogypsum stockpiles on the salt marshes of Huelva (SW Spain). Data in Brief 41, 107989. https://doi.org/10.1016/j.dib.2022.107989

2021

1. Arroyo M, Ruiz F, Campos JM, Bermejo J, González-Regalado ML, Rodríguez-Vidal J, Cáceres LM, Olías M, Abad M, Izquierdo T, Gómez P, Toscano A, Romero V & Gómez G (2021). Where did Christopher Columbus start? The estuarine scenario of a historical date. Estuarine, Coastal and Shelf Science 250, 107162. https://doi.org/10.1016/j.ecss.2020.107162

2. Arroyo M, Ruiz F, González-Regalado ML, Rodríguez Vidal J, Cáceres LM, Olías M, Campos JM, Fernández L, Abad M, Izquierdo T, Gómez P, Toscano A, Romero V, Gómez G. (2021). Natural and anthropic pollution episodes during the Late Holocene evolution of the Tinto River estuary (SW Spain). Scientia Marina 85, 113-123. https://doi.org/10.3989/scimar.05131.011

3. Cánovas CR, Basallote MD, Macías F, Olías M, Pérez-López R, Ayora C & Nieto JM (2021). Geochemical behaviour and transport of technology critical metals (TCMs) by the Tinto River (SW Spain) to the Atlantic Ocean. Science of The Total Environment 764, 143796. https://doi.org/10.1016/j.scitotenv.2020.143796

4. Cánovas CR, Macías F, Basallote MD, Olías M, Nieto JM & Pérez-López R (2021). Metal(loid) release from sulfide-rich wastes to the environment: the case of the Iberian Pyrite Belt (SW Spain). Current Opinion in Environmental Science & Health 20, 100240. https://doi.org/10.1016/j.coesh.2021.100240

5. Galván L, Olías M, Cerón JC & Fernández de Villarán R (2021). Inputs and fate of contaminants in a reservoir with circumneutral water affected by acid mine drainage. Science of The Total Environment 762, 143614. https://doi.org/10.1016/j.scitotenv.2020.143614

6. Gómez-Arias A, Yesares L, Caraballo M, Maleke M, Vermeulen D, Nieto JM, Van Heerden E & Castillo J (2021). Environmental and Geochemical characterization of alkaline mine wastes from Phalaborwa (Palabora) Complex, South Africa. Journal of Geochemical Exploration 224, 106757. https://doi.org/10.1016/j.gexplo.2021.106757

7. Guerrero JL, Gutiérrez-Álvarez I, Hierro A, Pérez-Moreno SM, Olías M & Bolívar JP (2021). Seasonal evolution of natural radionuclides in two rivers affected by acid mine drainage and phosphogypsum pollution. Catena 197,104978. https://doi.org/10.1016/j.catena.2020.104978

8. León R, Macías F, Cánovas CR, Pérez-López R, Ayora C, Nieto JM & Olías M (2021). Mine waters as a secondary source of rare earth elements worldwide: the case of the Iberian Pyrite Belt. Journal of Geochemical Exploration 224, 106742. https://doi.org/10.1016/j.gexplo.2021.106742

9. Millán-Becerro R, Cánovas CR, Pérez-López R, Macías F & León R (2021). Combined procedure of metal removal and recovery of technology elements from fertilizer industry effluents. Journal of Geochemical Exploration 221, 106698. https://doi.org/10.1016/j.gexplo.2020.106698

10. Olías M, Cánovas CR, Basallote MD (2021). Surface and Groundwater Quality Evolution in the Agrio and Guadiamar Rivers After the Aznalcollar Mine Spill (SW Spain): Lessons Learned. Mine Water and the Environment 40, 235-249. https://doi.org/10.1007/s10230-020-00713-7

11. Orden S, Macías F, Cánovas CR, Nieto JM, Pérez-López R & Ayora C (2021). Eco-sustainable passive treatment for mine waters: Full-scale and long-term demonstration. Journal of Environmental Management 280, 111699. https://doi.org/10.1016/j.jenvman.2020.111699

2020

1. Basallote MD, Borrero-Santiago AR, Cánovas CR, Hammer KM, Olsen AJ & Ardelan MV (2020). Trace metal mobility in sub-seabed sediments by CO2 seepage under high-pressure conditions. Science of the Total Environment 700, 134761. https://doi.org/10.1016/j.scitotenv.2019.134761

2. Cánovas CR, Basallote MD, Borrego P, Millán-Becerro R & Pérez-López R (2020). Metal partitioning and speciation in a mining-impacted estuary by traditional and passive sampling methods. Science of The Total Environment 722, 137905. https://doi.org/10.1016/j.scitotenv.2020.137905

3. Cánovas CR, Basallote MD & Macías F (2020). Distribution and availability of rare earth elements and trace elements in the estuarine waters of the Ría of Huelva (SW Spain). Environmental Pollution 267, 115506. https://doi.org/10.1016/j.envpol.2020.115506

4. Cánovas CR, Macías F, Olías M, Basallote MD, Pérez-López R, Ayora C & Nieto JM (2020). Release of technology critical metals during sulfide oxidation processes: the case of the Poderosa sulfide mine (south-west Spain). Environmental Chemistry 17(2), 93-104. https://doi.org/10.1071/EN19118

5. Cánovas CR, Nieto JM, Macías F, Basallote MD, Olías M, Pérez-López R & Ayora C (2020). Recovery of Critical Raw Materials from Acid Mine Drainage (AMD): The EIT-Funded MORECOVERY Project. In: Recovery of Byproducts from Acid Mine Drainage Treatment (Eds: Fosso-Kankeu E, Wolkersdorfer C & Burguess J), 219-234. Wiley, ISBN: 9781119620075. https://doi.org/10.1002/9781119620204.ch8

6. Guerrero JL, Gutiérrez-Álvarez I, Mosqueda F, Gázquez MJ, García-Tenorio R, Olías M & Bolívar JP (2020). Evaluation of the radioactive pollution in the salt-marshes under a phosphogypsum stack system. Environmental Pollution 258, 113729. https://doi.org/10.1016/j.envpol.2019.113729

7. Lozano A, Ayora C, Macías F, León R, Gimeno MJ & Auqué L (2020). Geochemical behavior of rare earth elements in acid drainages: Modeling achievements and limitations. Journal of Geochemical Exploration 216, 106577. https://doi.org/10.1016/j.gexplo.2020.106577

8. Mantero J, Thomas R, Holm E, Räaf C, Vioque I, Cánovas CR, García-Tenorio R, Forsell-Aronsson E & Isaksson M (2020). Pit lakes from Southern Sweden: natural radioactivity and elementary characterization. Scientific Reports 10, 13712. https://doi.org/10.1038/s41598-020-70521-0

9. Millán-Becerro R, Pérez-López R, Macías F & Cánovas CR (2020). Design and optimization of sustainable passive treatment systems for phosphogypsum leachates in an orphan disposal site. Journal of Environmental Management 275, 111251. https://doi.org/10.1016/j.jenvman.2020.111251

10. Moreno-González R, Cánovas CR, Olías M & Macías F (2020). Rare earth elements in a historical mining district (south-west Spain): Hydrogeochemical behaviour and seasonal variability. Chemosphere 253, 126742. https://doi.org/10.1016/j.chemosphere.2020.126742

11. Moreno González R, Cánovas CR, Olías M & Macías F (2020). Seasonal variability of extremely metal rich acid mine drainages from the Tharsis mines (SW Spain). Environmental Pollution 259, 113829. http://dx.doi.org/10.1016/j.envpol.2019.113829

12. Murillo-Barroso M, Montero-Ruiz I, Camalich MD, Martín-Socas D, Labaune M, Cattin F, Nieto JM & Martinón-Torres M (2020). Raw material procurement and selection in Southeast Iberia’s early metallurgy. Trabajos de Prehistoria 77, 87-112. https://doi.org/10.3989/tp.2020.12248

13. Olías M, Cánovas CR & Basallote MD (2020). Surface and Groundwater Quality Evolution in the Agrio and Guadiamar Rivers After the Aznalcóllar Mine Spill (SW Spain): Lessons Learned. Mine Water and the Environment 1-15. https://doi.org/10.1007/s10230-020-00713-7

14. Olías M, Cánovas CR, Macías F, Basallote MD & Nieto JM (2020). The Evolution of Pollutant Concentrations in a River Severely Affected by Acid Mine Drainage: Río Tinto (SW Spain). Minerals 10(7), 598. https://doi.org/10.3390/min10070598

15. Papaslioti EM, Pérez-López R, Parviainen A, Phan VTH, Marchesi C, Fernández-Martínez A, Garrido CJ, Nieto JM & Charlet L (2020). Effects of redox oscillations on the phosphogypsum waste in an estuarine salt-marsh system. Chemosphere 242, 125174. https://doi.org/10.1016/j.chemosphere.2019.125174

16. Ruiz F, Vidal JR, Cáceres LM, Olías M, González-Regalado ML, Campos JM, Bermejo J, Abad M, Izquierdo T & Carretero, MI (2020). Silver and copper as pollution tracers in Neogene to Holocene estuarine sediments from southwestern Spain. Marine pollution bulletin 150, 110704. https://doi.org/10.1016/j.marpolbul.2019.110704

17. Thomas R, Mantero J, Pérez-Moreno SM, Cánovas CR, Vioque I, Isaksson M, Forsell-Aronsson E, Holm E & García-Tenorio R (2020). 226Ra, 210Po and lead isotopes in a pit lake water profile in Sweden. Journal of Environmental Radioactivity 223-224, 106384. https://doi.org/10.1016/j.jenvrad.2020.106384

2019

1. Basallote MD, Cánovas CR, Olías M, Pérez-López R, Macías F, Carrero S, Ayora C & Nieto JM (2019). Mineralogically-induced metal partitioning during the evaporative precipitation of efflorescent sulfate salts from acid mine drainage. Chemical Geology 530, 119339. https://doi.org/10.1016/j.chemgeo.2019.119339

2. Bonnail E, Macías F & Osta V (2019). Ecological improvement assessment of a passive remediation technology for acid mine drainage: Water quality biomonitoring using bivalves. Chemosphere 219, 695-703. https://doi.org/10.1016/j.chemosphere.2018.12.037

3. Cánovas CR, Caro-Moreno D, Jiménez-Cantizano FA, Macías F & Pérez-López R (2019). Assessing the quality of potentially reclaimed mine soils: Environmental implications for the construction of a nearby water reservoir. Chemosphere 216, 19-30. https://doi.org/10.1016/j.chemosphere.2018.09.018

4. Cánovas CR, Chapron S, Arrachart Gb & Pellet-Rostaing S (2019). Leaching of rare earth elements (REEs) and impurities from phosphogypsum: A preliminary insight for further recovery of critical raw materials. Journal of Cleaner Production 219, 225-235. https://doi.org/10.1016/j.jclepro.2019.02.104

5. Cánovas CR, González de la Aleja C, Macías F, Pérez-López R, Basallote MD, Olías M & Nieto JM (2019). Mineral reactivity in sulphide mine wastes: influence of mineralogy and grain size on metal release. European Journal of Mineralogy 31(2), 263-273. https://doi.org/10.1127/ejm/2019/0031-2843

6. Conradi M, Sánchez-Moyano JE, Bhuiyan MKA, Rodríguez-Romero A, Galotti A, Basallote MD, DelValls, A, Parra G & Riba I (2019). Intraspecific variation in the response of the estuarine European isopod Cyathura carinata (Krøyer, 1847) to ocean acidification. Science of the Total Environment 683, 134-145. https://doi.org/10.1016/j.scitotenv.2019.05.227

7. Cruz-Hernández P, Carrero S, Pérez-López R, Fernandez-Martinez A, Lindsay MBJ, Dejoie C & Nieto JM (2019). Influence of As(V) on precipitation and transformation of schwertmannite in acid mine drainage-impacted waters. European Journal of Mineralogy 31(2), 237-245. https://doi.org/10.1127/ejm/2019/0031-2821

8. Cuadros J, Mavris Ch, Michalski J, Nieto JM, Bishop J & Fiore S (2019). Abundance and composition of kaolinite on Mars: Information from NIR spectra of rocks from acid-alteration environments, Riotinto, SE Spain. Icarus 330, 30-40. https://doi.org/10.1016/j.icarus.2019.04.027

9. El Zrelli R, Rabaoui L, Abda H, Daghbouj N, Pérez-López R, Castet S, Aigouy T, Bejaoui N & Courjault-Radé P (2019). Characterization of the role of phosphogypsum foam in the transport of metals and radionuclides in the Southern Mediterranean Sea. Journal of Hazardous Materials 363, 258-267. https://doi.org/10.1016/j.jhazmat.2018.09.083

10. Guerrero JL, Gutiérrez-Álvarez I, Mosqueda F, Olías M, García-Tenorio R & Bolívar JP (2019). Pollution evaluation on the salt-marshes under the phosphogypsum stacks of Huelva due to deep leachates. Chemosphere 230, 219-229. https://doi.org/10.1016/j.chemosphere.2019.04.212

11. López-Arce P, Garrido F, García-Guinea J, Voegelin A, Göttlicher J & Nieto JM (2019). Historical roasting of thallium- and arsenic-bearing pyrite: Current Tl pollution in the Riotinto mine area. Science of the Total Environment 648, 1263-1274. https://doi.org/10.1016/j.scitotenv.2018.08.260

12. Martínez NM, Basallote MD, Meyer A, Cánovas CR, Macías F & Schneider P (2019). Life cycle assessment of a passive remediation system for acid mine drainage: Towards more sustainable mining activity. Journal of Cleaner Production 211, 1100-1111. https://doi.org/10.1016/j.jclepro.2018.11.224

13. Millán-Becerro R, Pérez-López R, Macías F, Cánovas CR, Papaslioti EM & Basallote MD (2019). Assessment of metals mobility during the alkaline treatment of highly acid phosphogypsum leachates. Science of the total environment 660, 395-405. https://doi.org/10.1016/j.scitotenv.2018.12.305

14. Molina-González F, Nocete-Calvo F, Delgado-Huertas A, Cámara-Serrano JA, Martínez-Sánchez RM, Jiménez-Brobéil S, Miranda-León MT, Riquelme-Cantal JA, Spanedda L, Pérez-Bareas C, Lizcano-Prestel R, Nieto-Liñán JM, Nájera-Colino T, Granados-Torres A & Carrión-Méndez F (2019). Diet and environment in South-Eastern Iberia during the bronze age, based on isotope analysis of human remains. Oxford Journal of Archaeology 38, 189-213. https://doi.org/10.1111/ojoa.12164

15. Murillo-Barroso M, Montero-Ruiz I, Nieto JM, Camalich Massieu MD, Martín Socas D & Martinón-Torres M (2019). Trace elements and lead isotopic composition of copper deposits from the eastern part of the Internal Zone of the Betic Cordillera (SE Iberia): application to provenance of archaeological materials. Journal of Iberian Geology 45, 585-608. https://doi.org/10.1007/s41513-019-00111-1

16. Olías M, Cánovas CR, Basallote MD, Macías F, Pérez-López R, Moreno R, Millán-Becerro R & Nieto JM (2019). Causes and impacts of a mine water spill from an acidic pit lake (Iberian Pyrite Belt). Environmental Pollution 205, 127-136. https://doi.org/10.1016/j.envpol.2019.04.011

2018

1. Abril JM, San Miguel EG, Canovas CR, Casas-Ruiz M & Bolívar JP (2018). From floodplain to aquatic sediments: Radiogeochronological fingerprints in a sediment core from the mining impacted Sancho Reservoir (SW Spain). Science of the total environment 631-632, 866-878. https://doi.org/10.1016/j.scitotenv.2018.03.114

2. Basallote MD, Rodríguez-Romero A, De Orte MR, Del Valls TÁ & Riba I (2018). CO2 leakage simulation: effects of the pH decrease on fertilization and larval development of Paracentrotus lividus and sediment metals toxicity. Chemistry and Ecology 34, 1-21. https://doi.org/10.1080/02757540.2017.1396319

3. Cánovas CR, Macías F & Olías M (2018). Hydrogeochemical behavior of an anthropogenic mine aquifer: Implications for potential remediation measures. Science of the Total Environment 636, 85-93. https://doi.org/10.1016/j.scitotenv.2018.04.270

4. Cánovas CR, Macías F, Pérez-López R, Basallote MD & Millán-Becerro R (2018). Valorization of wastes from the fertilizer industry: Current status and future trends. Journal of Cleaner Production 174, 678-690. https://doi.org/10.1016/j.jclepro.2017.10.293

5. Cánovas CR, Macías F, Pérez-López R & Nieto JM (2018). Mobility of rare earth elements, yttrium and scandium from a phosphogypsum stack: Environmental and economic implications. Science of The Total Environment 618, 847-857. https://doi.org/10.1016/j.scitotenv.2017.08.220

6. Cánovas CR, Riera J, Carrero S & Olías M (2018). Dissolved and particulate metal fluxes in an AMD-affected stream under different hydrological conditions: The Odiel River (SW Spain). Catena 165, 414-424. https://doi.org/10.1016/j.catena.2018.02.020

7. Caraballo MA, Serna A, Macías F, Pérez-López R, Cánovas CR, Richter P & Becerra-Herrera M (2018). Uncertainty in the measurement of toxic metals mobility in mining/mineral wastes by standardized BCR®SEP. Journal of Hazardous Materials 360, 587-593. https://doi.org/10.1016/j.jhazmat.2018.08.046

8. De Orte MR, Bonnail E, Sarmiento AM, Bautista E, Basallote MD, Riba I, Del Valls A & Nieto JM (2018). Metal fractionation in marine sediments acidified by enrichment of CO⁠2: A risk assessment. Marine Pollution Bulletin 131, 611-619. https://doi.org/10.1016/j.marpolbul.2018.04.072

9. González RM, Olías M, Macías F, Cánovas CR & de Villarán RF (2018). Hydrological characterization and prediction of flood levels of acidic pit lakes in the Tharsis mines, Iberian Pyrite Belt. Journal of Hydrology 566, 807-817. https://doi.org/10.1016/j.jhydrol.2018.09.046

10. Mavris Ch, Cuadros J, Nieto JM, Bishop JL & Michalski JR (2018). Diverse mineral assemblages of acidic alteration in the Riotinto area (south-west Spain): implications for Mars. American Mineralogist 103, 1877-1890. https://doi.org/10.2138/am-2018-6330

11. Olías M, Cánovas CR, Basallote MD & Lozano A (2018). Geochemical behaviour of rare earth elements (REE) along a river reach receiving inputs of acid mine drainage. Chemical Geology 493, 468-477. https://doi.org/10.1016/j.chemgeo.2018.06.029

12. Padilla S, López-Gutiérrez JM, Sampath DM, Boski T, Nieto JM & García-León M (2018). Determination of denudation rates by the measurement of meteoric 10Be in Guadiana river sediment samples (Spain) by low-energy AMS. Journal of Environmental Radioactivity 189, 227-235. https://doi.org/10.1016/j.jenvrad.2018.04.016

13. Papaslioti EM, Pérez-López R, Parviainen A, Macías F, Delgado A, Garrido CJ, Marchesi C & Nieto JM (2018). Stable isotope insights into the weathering processes of a phosphogypsum disposal area. Water Research 140, 344-353. https://doi.org/10.1016/j.watres.2018.04.060

14. Papaslioti EM, Pérez-López R, Parviainen A, Sarmiento AM, Nieto JM, Marchesi C & Garrido CJ (2018). Effects of seawater mixing on the mobility of trace elements in acid phosphogypsum leachates. Marine Pollution Bulletin 127, 695-703. https://doi.org/10.1016/j.marpolbul.2018.01.001

15. Parviainen A, Marchesi C, Suárez-Grau JM, Garrido CJ, Pérez-López R, Nieto JM & Cárdenas-Cobo G (2018). Unraveling the impact of chronic exposure to metal pollution through human gallstones. Science of The Total Environment 624, 1031-1040. https://doi.org/10.1016/j.scitotenv.2017.12.224

16. Pérez-López R, Carrero S, Cruz-Hernández P, Asta MP, Macías F, Cánovas CR, Guglieri C & Nieto JM (2018). Sulfate reduction processes in salt marshes affected by phosphogypsum: implications for managing pore-water quality. Journal of Hazardous Materials 350, 154-161. https://doi.org/10.1016/j.jhazmat.2018.02.001

17. Pérez-Moreno SM, Gázquez MJ, Pérez-López R, Vioque I & Bolívar JP (2018). Assessment of natural radionuclides mobility in a phosphogypsum disposal area. Chemosphere 211, 775-783. https://doi.org/10.1016/j.chemosphere.2018.07.193

18. Torres E, Lozano A, Macías F, Gómez-Arias A, Castillo J & Ayora C (2018). Passive elimination of sulfate and metals from acid mine drainage using combined limestone and barium carbonate systems. Journal of Cleaner Production 182, 114-123. https://doi.org/10.1016/j.jclepro.2018.01.224

2017

1. Bonnail E, Pérez-López R, Sarmiento AM, Nieto JM & DelValls TÁ (2017). A novel approach for acid mine drainage pollution biomonitoring using rare earth elements bioaccumulated in the freshwater clam Corbicula fluminea. Journal of Hazardous Materials 338, 466-471. https://doi.org/10.1016/j.jhazmat.2017.05.052

2. Cánovas CR, Macías F, Olías M, Pérez-López R & Nieto JM (2017). Metal-fluxes characterization at a catchment scale: Study of mixing processes and end-member analysis in the Meca River watershed (SW Spain). Journal of Hydrology 550, 590-602. https://doi.org/10.1016/j.jhydrol.2017.05.037

3. Cánovas CR, Pérez-López R, Macías F, Champron S, Nieto JM & Pellet-Rostaing S (2017). Exploration of fertilizer industry wastes as potential source of critical raw materials. Journal of Cleaner Production 143, 497-505. https://doi.org/10.1016/j.jclepro.2016.12.083

4. Carrero S, Fernandez-Martinez A, Pérez-López R, Lee D, Aquilanti G, Poulain A, Lozano A & Nieto JM (2017). The nanocrystalline structure of basaluminite, an aluminum hydroxide sulfate from acid mine drainage. American Mineralogist 102(12), 2381-2389. https://doi.org/10.2138/am-2017-6059

5. Carrero S, Fernandez-Martinez A, Pérez-López R, Poulain A, Salas-Colera E & Nieto JM (2017). Arsenate and Selenate Scavenging by Basaluminite: Insights into the Reactivity of Aluminum Phases in Acid Mine Drainage. Environmental Science and Technology 51(1), 28-37. https://doi.org/10.1021/acs.est.6b03315

6. Goulding TA, De Orte MR, Szalaj D, Basallote MD, Del Valls TA & Cesar A (2017). Assessment of the environmental impacts of ocean acidification (OA) and carbon capture and storage (CCS) leaks using the amphipod Hyale youngi. Ecotoxicology 26(4), 521-533. https://doi.org/10.1007/s10646-017-1783-6

7. Jofre-Meléndez R, Torres E, Ramos-Arroyo YR, Galván L, Cánovas CR & Ayora C (2017). Reconstruction of an acid water spill in a mountain reservoir. Water 9(9), 613. https://doi.org/10.3390/w9090613

8. Lecomte KL, Sarmiento AM, Borrego J & Nieto JM (2017). Rare earth elements mobility processes in an AMD-affected estuary: Huelva Estuary (SW Spain). Marine Pollution Bulletin 121(1-2), 282-291. https://doi.org/10.1016/j.marpolbul.2017.06.030

9. Macías F, Cánovas CR, Cruz-Hernández P, Carrero S, Asta MP, Nieto JM & Pérez-López R (2017). An anomalous metal-rich phosphogypsum: Characterization and classification according to international regulations. Journal of Hazardous Materials 5(331), 99-108. https://doi.org/10.1016/j.jhazmat.2017.02.015

10. Macías F, Pérez-López R, Caraballo MA, Cánovas CR & Nieto JM (2017). Management strategies and valorization for waste sludge from active treatment of extremely metal-polluted acid mine drainage: A contribution for sustainable mining. Journal of Cleaner Production 141, 1047-1066. https://doi.org/10.1016/j.jclepro.2016.09.181

11. Macías F, Pérez-López R, Caraballo MA, Sarmiento AM, Cánovas CR, Nieto JM, Olías M & Ayora C (2017). A geochemical approach to the restoration plans for the Odiel River basin (SW Spain), a watershed deeply polluted by acid mine drainage. Environmental Science and Pollution Research 24(5), 4506-4516. https://doi.org/10.1007/s11356-016-8169-9

12. Parviainen A, Roman-Alpiste MJ, Marchesi C, Suárez-Grau JM & Pérez-López R (2017). New insights into the metal partitioning in different microphases of human gallstones. Journal of Trace Elements in Medicine and Biology 44, 339-348. https://doi.org/10.1016/j.jtemb.2017.09.013

13. Puga E, De Federico AD, Fanning M, Nieto JM, Martínez-Conde JA, Díaz-Puga MA, Lozano JA, Natali C & Beccaluva L (2017). The Betic Ophiolites and the Mesozoic evolution of the western Tethys. Geosciences 7(2), 31. https://doi.org/10.3390/geosciences7020031

14. Romero-Hermida I, Santos A, Pérez-López R, García-Tenorio R, Esquivias L & Morales-Flórez V (2017). New method for carbon dioxide mineralization based on phosphogypsum and aluminium-rich industrial wastes resulting in valuable carbonated by-products. Journal of CO2 Utilization 18, 15-22. https://doi.org/10.1016/j.jcou.2017.01.002

15. Sestu M, Navarra G, Carrero S, Valvidare SM, Aquilanti G, Pérez-Lopez R & Fernandez-Martinez A (2017). Whole-nanoparticle atomistic modeling of the schwertmannite structure from total scattering data. Journal of Applied Crystallography 50, 1617-1626. https://doi.org/10.1107/S160057671701336X

16. Yesares L, Sáez R, Ruiz De Almodóvar G, Nieto JM, Gómez C & Ovejero G (2017). Mineralogical evolution of the Las Cruces gossan cap (Iberian Pyrite Belt): From subaerial to underground conditions. Ore Geology Reviews 80, 377-405. https://doi.org/10.1016/j.oregeorev.2016.05.018

17. Zuluaga MC, Norini G, Ayuso R, Nieto JM, Lima A, Albanese S & De Vivo B (2017). Geochemical mapping, environmental assessment and Pb isotopic signatures of geogenic and anthropogenic sources in three localities in SW Spain with different land use and geology. Journal of Geochemical Exploration 181, 172-190. https://doi.org/10.1016/j.gexplo.2017.07.011

2016

1. Ayora C, Macías F, Torres E, Lozano A, Carrero S, Nieto JM, Pérez-López R, Fernández-Martínez A & Castillo-Michel H (2016). Recovery of Rare Earth Elements and Yttrium from Passive-Remediation Systems of Acid Mine Drainage. Environmental Science and Technology 50(15), 8255-8262. https://doi.org/10.1021/acs.est.6b02084

2. Bonnail E, Sarmiento AM, DelValls TA, Nieto JM & Riba I (2016). Assessment of metal contamination, bioavailability, toxicity and bioaccumulation in extreme metallic environments (Iberian Pyrite Belt) using Corbicula fluminea. Science of the Total Environment 544, 1031-1044. https://doi.org/10.1016/j.scitotenv.2015.11.131

3. Cánovas CR, Macías F & Pérez-López R (2016). Metal and acidity fluxes controlled by precipitation/dissolution cycles of sulfate salts in an anthropogenic mine aquifer. Journal of Contaminant Hydrology 188, 29-43. https://doi.org/10.1016/j.jconhyd.2016.02.005

4. Cánovas CR, Olías M, Macías F, Torres E, San Miguel EG, Galván L, Ayora C & Nieto JM (2016). Water acidification trends in a reservoir of the Iberian Pyrite Belt (SW Spain). Science of the Total Environment 541, 400-411. https://doi.org/10.1016/j.scitotenv.2015.09.070

5. Caraballo MA, Macías F, Nieto JM & Ayora C (2016). Long term fluctuations of groundwater mine pollution in a sulfide mining district with dry Mediterranean climate: Implications for water resources management and remediation. Science of the Total Environment 539, 427-435. https://doi.org/10.1016/j.scitotenv.2015.08.156

6. Cruz-Hernández P, Pérez-López R, Parviainen A, Lindsay MBJ & Nieto JM (2016). Trace element-mineral associations in modern and ancient iron terraces in acid drainage environment. Catena 147, 386-393. https://doi.org/10.1016/j.catena.2016.07.049

7. Galván L, Olías M, Cánovas CR, Sarmiento AM & Nieto JM (2016). Hydrological modeling of a watershed affected by acid mine drainage (Odiel River, SW Spain). Assessment of the pollutant contributing areas. Journal of Hydrology 540, 196-206. https://doi.org/10.1016/j.jhydrol.2016.06.005

8. Olías M, Nieto JM, Pérez-López R, Cánovas CR, Macías F, Sarmiento AM & Galván L (2016). Controls on acid mine water composition from the Iberian Pyrite Belt (SW Spain). Catena 137, 12-23. https://doi.org/10.1016/j.catena.2015.08.018

9. Parviainen A, Suárez-Grau JM, Pérez-López R, Nieto JM, Garrido CJ & Cobo-Cárdenas G (2016). Combined microstructural and mineralogical phase characterization of gallstones in a patient-based study in SW Spain. Implications for environmental contamination in their formation. Science of the Total Environment 15(573), 433-443. https://doi.org/10.1016/j.scitotenv.2016.08.110

10. Pérez-López R, Macías F, Cánovas CR, Sarmiento AM & Pérez-Moreno SM (2016). Pollutant flows from a phosphogypsum disposal area to an estuarine environment: An insight from geochemical signature. Science of The Total Environment 553, 42-51. https://doi.org/10.1016/j.scitotenv.2016.02.070

11. Sarmiento AM, Bonnail E, Nieto JM & DelValls TÁ (2016). Bioavailability and toxicity of metals from a contaminated sediment by acid mine drainage: linking exposure–response relationships of the freshwater bivalve Corbicula fluminea to contaminated sediment. Environmental Science and Pollution Research 23(22), 22957-22967. https://doi.org/10.1007/s11356-016-7464-9

2015

1. Basallote MD, Rodríguez-Romero A, De Orte MR, Del Valls TÁ & Riba I (2015). Evaluation of the threat of marine CO2 leakage-associated acidification on the toxicity of sediment metals to juvenile bivalves. Aquatic Toxicology 166, 63-71. https://doi.org/10.1016/j.aquatox.2015.07.004

2. Cánovas CR, Peiffer S, Macías F, Olías M & Nieto JM (2015). Geochemical processes in a highly acidic pit lake of the Iberian Pyrite Belt (SW Spain). Chemical Geology 395, 144-153. https://doi.org/10.1016/j.chemgeo.2014.12.007

3. Carrero S, Pérez-López R, Fernandez-Martinez A, Cruz-Hernández P, Ayora C & Poulain A (2015). The potential role of aluminium hydroxysulphates in the removal of contaminants in acid mine drainage. Chemical Geology 417, 414-423. https://doi.org/10.1016/j.chemgeo.2015.10.020

4. Contreras M, Pérez-López R, Gázquez MJ, Morales-Flórez V, Santos A, Esquivias L & Bolívar JP (2015). Fractionation and fluxes of metals and radionuclides during the recycling process of phosphogypsum wastes applied to mineral CO₂ sequestration. Waste Management 45, 412-419. https://doi.org/10.1016/j.wasman.2015.06.046

5. Olías M & Nieto JM (2015). Background conditions and mining pollution throughout history in the Río Tinto (SW Spain). Environments 2, 295-316. http://dx.doi.org/10.3390/environments2030295

6. Parviainen A, Cruz-Hernández P, Pérez-López R, Nieto JM & Delgado-López JM (2015). Raman identification of Fe precipitates and evaluation of As fate during phase transformation in Tinto and Odiel River Basins. Chemical Geology 398, 22-31. https://doi.org/10.1016/j.chemgeo.2015.01.022

7. Pérez-López R, Nieto JM, de la Rosa JD & Bolívar JP (2015). Environmental tracers for elucidating the weathering process in a phosphogypsum disposal site: Implications for restoration. Journal of Hydrology 529(3), 1313-1323. https://doi.org/10.1016/j.jhydrol.2015.08.056

8. Yesares L, Aiglsperger T, Sáez R, Almodóvar GR, Nieto JM, Proenza JA, Gómez C & Escobar JM (2015). Gold Behavior in Supergene Profiles Under Changing Redox Conditions: The Example of the Las Cruces Deposit, Iberian Pyrite Belt. Economic Geology 110, 2109-2126. https://doi.org/10.2113/econgeo.110.8.2109

9. Yesares L, Sáez R, Nieto JM, De Almodóvar GR, Gómez C & Escobar JM (2015). The Las Cruces deposit, Iberian Pyrite Belt, Spain. Ore Geology Reviews 66, 25-46. https://doi.org/10.1016/j.oregeorev.2014.10.019